Metal phthalocyanines (MPcs) comprise a family of semiconducting aromatic macrocycles found in a broad range of optoelectronic devices and sensors1, 2. & Sigman, M. E. Fluorescence decay study of anisotropic rotations of substituted pyrenes physisorbed and chemically attached to a fumed silica surface. We can determine that water had the highest solubility because it ran the quickest through the filter and had the lowest ++, value. Kreuer, K. On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells. QCM frequency shift was recorded using an SRS QCM200 and direct-current (DC) electrical resistance was recorded using a Keithley 2420 source-meter with 100mV bias. To prepare these complexes, the phthalocyanine synthesis is conducted in the presence of metal salts. The behavior of \({k}_{1-1}\) and \(\,{k}_{1-2}\) resembles the trend in \({{\rm{\tau }}}_{2}/{{\rm{\tau }}}_{1}\) (Fig. Finally, we demonstrate the value of using a multi-modal approach for understanding mechanisms of sensing and referencing optical and electrical changes to the mass of adsorbed water on the surface of the sensor, as well as identification of the most sensitive detection modes for analyte identification. Thin Solid Films Mohamed E El-Khouly, Cem Gl, Morad M. El-Hendawy, Sekan Yeilot, Mahmut Durmu. Google Scholar. Water exposure leads to significant decreases in k between 550 and 650nm and decreases in n between 450 and 900nm. The https:// ensures that you are connecting to the 2018 Jul 18;10(28):24201-24208. doi: 10.1021/acsami.8b07377. An official website of the United States government. To further investigate electrical response of CuPcTs, EIS was performed to study dielectric properties of the CuPcTs film in the 1Hz 8MHz frequency range during exposure to H2O. Typical bulk packaging includes palletized plastic 5 gallon/25 kg. If you do not agree to the use of cookies, you should not navigate The requested specifications are not available. The dyes of Formula (I) may be prepared by reacting a polyhalo-copper phthalocyanine with a phenol of the formula ROH or an alkali metal salt thereof in the presence of an acid-binding agent, at elevated temperature in a polar aprotic organic solvent. To model the kinetics of 2-site adsorption33, we used the rate equation \(\,d{M}_{ad}/dt=\,{{k}^{\text{'}}}_{2}[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}][{M}_{e1}-{M}_{t1}][{M}_{e2}-{M}_{t2}]\), where \({{k}^{\text{'}}}_{3}\) is the third order rate constant,\(\,{M}_{ei}\,\)is the mass adsorbed at equilibrium at a given P/P0 at site \(i\) and \({M}_{ti}\) is the mass adsorbed at time t at a given P/P0 at site \(i\). Copper (atomic symbol: Cu, atomic number: 29) is a Block D, Group 11, Period 4 element with an atomic weight of 63.546. Values of \(\,\theta \),\(\,A\), and \({\rm{\tau }}\) are shown in FiguresS1 and S2. [41] Oral LD50 in mammals is estimated to be greater than 5g per kg, with no ill effects found at that level of ingestion,[17] for chronic ingestion estimated dose of low concern was 0.2mg/kg per day in rats. Although the units for first and second order rate constants are different, the PSO rate constant \({k}_{2}\) clearly resembles behavior of the PFO rate constant \(\,{k}_{1-1}\), and its value lies between the values of \(\,{k}_{1-1}\) and \({k}_{1-2}\) because \(\,{k}_{2}\) describes a combination of two sequentially-occurring reactions with rates \(\,{k}_{1-1}\,\,\)and \(\,{k}_{1-2}\). Red lines indicate examples of double exponential fits. 28, 289302 (1975). examined by femtosecond and nanosecond laser flash photolysis to explore its photoinduced intramolecular events from the Peak positions of the B- and Q-bands shift to lower energies and the probability of * transitions decrease by 50% as RH increases from 3% to 90%. 2020 Feb 15;227:117621. doi: 10.1016/j.saa.2019.117621. - Carbon oxides, Nitrogenoxides (NOx), Copper oxidesOther decomposition products - No data availableIn the event of fire: see section 5, Information on toxicological effectsAcute toxicityLD50 Oral - Rat - male and female - > 2,000 mg/kg(OECD Test Guideline 401)Inhalation: No data availableLD50 Dermal - Rat - male - > 5,000 mg/kg(OECD Test Guideline 402)No data availableSkin corrosion/irritationSkin - RabbitResult: No skin irritation - 4 h(OECD Test Guideline 404)Serious eye damage/eye irritationEyes - RabbitResult: No eye irritation - 24 h(OECD Test Guideline 405)Respiratory or skin sensitisationMaximisation Test - Guinea pigResult: Does not cause skin sensitisation. Bright color and strong coloring power. Error bars are propagated double exponential fitting errors. ACS Appl Mater Interfaces. In the approximation \(\,[{M}_{e1}-{M}_{t1}]\approx [{M}_{e2}-{M}_{t2}]\), the pseudo-second order (PSO) rate equation34 becomes \(d{M}_{ad}/dt=\,{k}_{2}{({M}_{e}-{M}_{t})}^{2}\). Cu 2+ Pc 2. A LevenbergMarquardt algorithm was used for fitting oscillator parameters. Hamam, K. J., Al-Amar, M. M., Mezei, G., Guda, R. & Burns, C. High dielectric constant response of modified copper phthalocyanine. 37, 30793086 (2003). ACS Applied Materials & Interfaces At low RH, capacitance increases due to an increase in average dielectric constant caused by adsorption of H2O and the formation of electrical double layers composed of hydrated Na+ ions. Article This website requires certain cookies to work and uses other cookies to help you have the best experience. Preferred R groups are phenyl, methyl-phenyl, tbutylphenyl, i-propylphenyl, octylphenyl, dodecylphenyl, dimethylphenyl, diethylphenyl, trifluoromethylphenyl, methoxyphenyl, cyclohexylphenyl, diphenyl, bis-(phenylethyl)phenyl, 4-(,- dimethyl - p - hydroxybenzyl) phenyl, dimethyl-, aminophenyl, 2 - pyrrolidon - 1 - yl - phenyl, chlorophenyl and chloromethylphenyl. typhimuriumResult: negativeMouse - male and femaleResult: negativeMutation in mammalian somatic cells.CarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.NTP: No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.OSHA: No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.Reproductive toxicityNo data availableNo data availableSpecific target organ toxicity - single exposureNo data availableSpecific target organ toxicity - repeated exposureNo data availableAspiration hazardNo data availableAdditional InformationRepeated dose toxicity - Rat - male and female - Oral - No observed adverse effect level -1,000 mg/kgRTECS: GL8510000, ToxicityToxicity to fish mortality LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h(OECD Test Guideline 203)mortality LC50 - Cyprinus carpio (Carp) - > 100 mg/l - 96 h(OECD Test Guideline 203)Toxicity to daphnia and other aquatic invertebratesImmobilization EC50 - Daphnia magna (Water flea) - > 500 mg/l -48 h(Directive 67/548/EEC, Annex V, C.2. 1c) and showed no significant dependence on water vapor pressure, desorption kinetics were not analyzed in terms of PFO and PSO models. Under constant humidity conditions, \([{{\rm{H}}}_{2}{{\rm{O}}}_{ad}]\,\,\)is constant and absorbed into a new rate constant \(\,{k}_{2}\), where \(\,{k}_{2}={k}_{3}^{\text{'}}[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}]\). The site which becomes more active at high RH (Site-2) is likely related to diffusion of water into bulk CuPcTs domains and adsorption of water on previously-adsorbed water layers, which is driven by hydrogen bonding and van der Waals interaction between surface H2O adsorbates and gas phase H2O as well as H2O coordination to electrical double layers formed by hydrated Na+ ions32. doi: 10.1016/j.apsusc.2004.11.036. Copper was first discovered by Early Man prior to 9000 BC. Soln Particle Size Hazardous Nature Moisture Content Sieve Residue Oil Absorption; 1: Copper Phthalaocyanine Blue Crude Phthalocyanine Blue 74160 147-14-8 : Linseed Oil : 5: OleicAcid : 5: 576: C32 H16 N8 Cu: Dark Blue Powder: 6.0 - 7.5: 1 %: 1000 PPM Max 2011 Nov;11 (11):9641-4. doi: 10.1166/jnn.2011.5323. [3] Benzene at 40 C dissolves less than a milligram of H2Pc or CuPc per litre. 15 (IEEE). Zagal, J., Bindra, P. & Yeager, E. A mechanistic study of O2 reduction on water soluble phthalocyanines adsorbed on graphite electrodes. N.L. Documents(Note: Some products will not have analytical charts available. 0. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. Gloves must be inspected prior to use. Sizun, T., Bouvet, M. & Suisse, J.-M. Humidity effect on ammonia sensing properties of substituted and unsubstituted cobalt phthalocyanines. Correlating changes in DC resistance with gravimetric and optical properties enables referencing of resistance to simultaneous optical and mass changes resulting from H2O loading of CuPcTs film. Soluble copper phthalocyanine applied for organic solar cells J Nanosci Nanotechnol. 8, 7597 (2008). CuPc has also been investigated as a component of organic field-effect transistors. Aqueous solubility of copper phthalocyanine-3,4',4',4"'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Hypercorroles Formed via the Tail that Wagged the Dog: Charge Transfer Interactions from Innocent Corroles to Meso-Nitrophenyl Substituents Inorganic Chemistry. Aqueous solubility of copper phthalocyanine-3,4',4,4'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. The results suggest that rapid H2O adsorption takes place at hydrophilic sulfonyl/salt groups on domain surfaces at low RH, while slow adsorption and diffusion of H2O into CuPcTs crystallites leads to a mixed CuPcTs-H2O phase at RH > 60%, resulting in high frequency dielectric screening of the film by water and dissociation of Na+ from CuPc(SO3-)4 ions. Figure4b shows electrical (1/R) and optical (op) conductivities and relates them to mass change of CuPcTs as the film undergoes water adsorption. 2017 May 10;9(18):15880-15886. doi: 10.1021/acsami.7b03128. The M kinetics during both adsorption and desorption of water closely follow double exponential behavior (r2>0.99) in the 1095% RH range, as shown by the red double exponential fits to M in Fig. Since the electron transfer from the singlet ZnPc to Excludes regulated items and items that ship on ice. The excitation transfer from the singlet BODIPY to )Toxicity to algae static test EC50 - Desmodesmus subspicatus (green algae) - > 100mg/l - 72 h(OECD Test Guideline 201)Toxicity to bacteria Respiration inhibition EC50 - Sludge Treatment - > 10,000 mg/l - 3h(OECD Test Guideline 209)Persistence and degradabilityBiodegradability aerobic - Exposure time 28 dResult: 5 % - Not biodegradable(OECD Test Guideline 301C)Bioaccumulative potentialNo data availableMobility in soilNo data availableResults of PBT and vPvB assessmentPBT/vPvB assessment not available as chemical safety assessment not required/notconductedOther adverse effectsNo data available. Rinse mouth with water.Most important symptoms and effects, both acute and delayedThe most important known symptoms and effects are described in the labelling (see section2 and/or in section 11Indication of any immediate medical attention and special treatment neededNo data available, Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Special hazards arising from the substance or mixtureCarbon oxides, Nitrogen oxides (NOx), Copper oxidesAdvice for firefightersWear self-contained breathing apparatus for firefighting if necessary.Further informationNo data available. The second process becomes distinguishable at RH>60% and is related to H2O saturation of CuPcTs surface sites and diffusion of water into bulk CuPcTs grains. CuPc has often been investigated in the context of molecular electronics. 2008;8:7597. ZnPc in tetrahydrofuran. We use several isotherm models to examine the kinetics of water adsorption, which reveals a complex adsorption mechanism that involves at least two different adsorption sites, including a dominant process which is active in the entire measurement range (~095% RH) and one which becomes active for RH>60%. Avoid breathing vapours, mist or gas.For personal protection see section 8.Environmental precautionsNo special environmental precautions required.Methods and materials for containment and cleaning upSweep up and shovel. [27][28] Photon to electron conversion efficiency in such system reaches approximately 5%. CuPc belongs to the D4h point group. Electrical properties and gas response in alternate layer-by-layer films of copper phthalocyanine dyes. The CuPcTs-H2O interaction can be tracked using a combination of gravimetric, optical, and electrical sensing modes, enabling accurate (2.5%) sensing in the ~095% RH range with a detection limit of less than 0.1% RH. Sauerbrey, G. Verwendung von Schwingquarzen zur Wgung dnner Schichten und zur Mikrowgung. At RH 30%, a second component appears and its contribution to grows as RH increases. Pigment Blue 15:2,[5][6] copper phthalocyanine blue,[7] copper tetrabenzoporphyrazine,[8] Cu-phthaloblue,[9] P.B.15.2,[10][11][12] C.I. Adsorption at these sites does not lead to significant changes in optoelectronic properties of the film. PMC Statistical analysis identified at least two principal components which adequately describe the optical response of CuPcTs to water vapor. 300750 nm), which clearly is an advantage for capturing solar energy. Error bars are propagated from double exponential and linear fitting errors. volume7, Articlenumber:9921 (2017) Product Number: All applicable American Elements product codes, e.g. The plot of \(\mathrm{ln}({M}_{e}-{M}_{t})\) vs. t is shown in Fig. By visiting (, Scheme for water uptake into CuPcTs domain. It is available in both alpha and beta forms. Epub 2012 Feb 3. This site needs JavaScript to work properly. Figure3a shows extinction coefficient (k) (top panel) and index of refraction (n) (bottom panel) as a function of wavelength () at different RH levels. use 1. data. Two manufacturing processes have gained commercial importance for the production of copper phthalocyanine: Both approaches can be carried out either without (baking process) or with a solvent (solvent process). Spectroscopic ellipsometry (SPE) measurements were obtained at 1.5nm steps from 2751000nm at 75 incident angle using a J.A. Bethesda, MD 20894, Web Policies Use the Previous and Next buttons to navigate three slides at a time, or the slide dot buttons at the end to jump three slides at a time. The ratio of A2/A1 corresponds to the relative activity of adsorbates at site 2 relative to site 1, while 2/1 corresponds to timescale associated with the adsorption rate at site 2 relative to the adsorption rate at site 1. ACS Nano. Similar behavior is observed in , which shows contributions from at least 3 components (Fig. 2022. Many phthalocyanine compounds are, thermally, very stable and do not melt but can be sublimed. CAS The quaternary ammonium salts of these sulfonic acids are used as solvent dyes because of their solubility in organic solvents, such as Solvent Blue 38 and Solvent Blue 48. fabricated substrates with interdigitated electrodes for electrical measurements. See more Copper products. Visit our updated, This website requires certain cookies to work and uses other cookies to help you have the best experience. Google Scholar. Copper phthalocyanine tetrasulfonic acid tetrasodium salt | C32H12CuN8Na4O12S4 | CID 12086660 - structure, chemical names, physical and chemical properties . (b) Reaction rate constants for first (k11) and second (k12) pseudo-first order kinetic processes identified in (a), shown with exponential fits. Thin Solid Films Multi-mode humidity sensing with water-soluble copper phthalocyanine for increased sensitivity and dynamic range. Readilysolublephthalocyanines(alsoincludingotherionsthan 3c). 185, 2939 (2001). This research was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility. Cu2+Pc2. )4 ions are left with 4 charges. Bethesda, MD 20894, Web Policies The density is 1.94~2.05g/cm3. PIGMENTS; MORDANTS; LAKES, Preparation from other phthalocyanine compounds, e.g. Similar behavior is observed in the RH dependence of k (FigureS5b). A flow cell with optical windows was used to control the sample environment during SPE measurements. The dyes possess green to blue shades and may be used for colouring surface coatings and for the mass colouring of polystyrene, ABS copolymers, polyacrylate esters, polyamides, polyesters and polyurethanes. By Elsevier Science pp-115 (2003). Solubility In Water Specific Gravity PH of % Aq. It is composed of four isoindole units linked by a ring of nitrogen atoms. CuPc belongs to the D4h point group. As a result, MPc-based organic solar cells with power conversion efficiencies at or below 5% have been developed. Periodic table of the elements, materials science and academic information, elements and advanced materials data, scientific presentations and all pages, designs, concepts, logos, and color schemes herein are the copyrighted proprietary rights and intellectual property of American Elements. Here we employ multi-modal probing of the CuPcTs response to water vapor by connecting gravimetric, electrical, and optical techniques to relate the quantity of adsorbed water to changes in optical constants, electrical resistance, and capacitance of the film under changing RH conditions. yj> Fit lines correspond to colors used in the bar graph. 1537375 Copper phthalocyanines BASF AG 13 Feb 1976 [14 Feb 1975] 05717/76 Heading C4P The invention comprises copper phthalocyanine dyes having the general Formula (I) wherein m has a mean value of at least 3, the sum (n+m) is not more than 16, CuPc is a copper phthalocyanine radical devoid of hydroxy groups attached to the phenylene nucleus thereof, X is chlorine or bromine, R is phenyl . The kinetic study of energy transfer measured by monitoring the decay of the BODIPY emission, revealed fast energy transfer (5.90 1010 s-1) in the molecular pentad. Here, sensitivity refers to the smallest RH changes detectable by the particular measurement technique at a given water vapor pressure P/P0 as estimated from the signal to noise ratio (SNR) for each response. PCA results indicate that significant changes in optical constants which occur near 6070% RH are a result of the emergence of a secondary process which becomes active after significant H2O adsorption has taken place in the film, which suggests that the secondary principal component is related to dielectric screening caused by H2O saturation of CuPcTs domains. 74160,[13][14][15] and British Rail Blue. Water crowding at hydrophilic sulfonyl/salt groups leads to dissociation of Na, Multimode sensing and detection limits. Accessibility Double exponential behavior is typically observed in sorbents which contain sites associated with two or more distinct energies29, 30. The newly synthesized compounds (BS, BS-1, BS-1-CN), copper(II), manganese(III), phthalocyanines (BS-1-Cu, BS-1-Mn) and their water soluble derivatives (BS-1-CuQ, BS-1-MnQ) were characterized by standard methods.All steps of the synthetic procedures were given in Figs. Optics & Laser Technology It is present in a wide variety of products,[20] such as color deposition hair conditioner,[21] eye patches, parfum, shampoo, skin-care products, soap, sunscreen, tattoo ink,[22] toothpaste. At RH>60%, the value of C1 begins decreasing. Scheme for water uptake into CuPcTs domain. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY. [17] No evidence indicates carcinogenic effects. Results from double exponential and PFO kinetic models suggest that at least 2 distinct sites are active during H2O adsorption on CuPcTs. Surface Functionalization with Copper Tetraaminophthalocyanine Enables Efficient Charge Transport in Indium Tin Oxide Nanocrystal Thin Films. RSC Adv. Phthalocyanines are a class of pigments that are known for their ability to abso Lecture notes, lecture all - Chapter 15-20, Chapter 6 (Reactions of Alkenes)- Discussion Answers, Organic Chemistry: Dat Organic Chem Reaction Summary. 1c. Muckley, E.S., Jacobs, C.B., Vidal, K. et al. -, Zagal J, Bindra P, Yeager E. A mechanistic study of O2 reduction on water soluble phthalocyanines adsorbed on graphite electrodes. Phys. A Nyquist plot of imaginary vs. real impedance (black points, FigureS9) shows a suppressed single semi-circle, suggesting that a modified Randles equivalent circuit model is appropriate for fitting (inset in Fig. and K.V. Precautions for safe handlingProvide appropriate exhaust ventilation at places where dust is formed.For precautions see section 2.Conditions for safe storage, including any incompatibilitiesKeep container tightly closed in a dry and well-ventilated place.Keep in a dry place.Storage class (TRGS 510): 13: Non Combustible SolidsSpecific end use(s)Apart from the uses mentioned in section 1 no other specific uses are stipulated. A.H PbXW|u 7D0c2AGDA."`yp]K ah+Wr77t/7}KmM+bwqMNtYn%el_BjTt:+,.d]}UTZg:# Your email address will not be stored! cobaltphthalocyanineamine complex, SOLUBLE COPPER PHTHALOCYANINE DYES AND THEIR APPLICATION, Poly(oxyalkylene) modified phthalocyanine colorants, Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein, Thermoplastic materials containing near infrared fluorophores, Organic solvent based ink for invisible marking/identification, Security document and method using invisible coded markings, Polyester compositions containing near infrared absorbing materials to improve reheat, Fiber coating composition having an invisible marker and process for making same, Method for marking items for identification, New phthalocyanine compounds, their manufacturing processes and the near infrared absorbing materials they contain, Water-based ink, ink set, ink jet recording method, ink cartridge, recording unit and ink jet recording apparatus, Method for tagging thermoplastic materials with near infrared fluorophores, Method for detecting and separating thermoplastic containers with near infrared fluorosphores, Triphendioxazine dyes, methods for their manufacture and their use for dyeing cellulosic substrates, Reactive dyes, processes for their manufacture and their use, Process for preparing water-soluble monoazo pyrazolone compound, Water-soluble disazo compounds, process for their preparation and their use as dyestuffs, Novel azomethine compound and its preparation, A process for the preparation of aluminium-heavy metal mixed complexes, Copper complex formazan compound, its preparation and use thereof, Pyrazolo(4,3-d)pyrimidine derivative, its preparation, cholesterol-lowering agent containing it, its intermediate and its preparation, Copper complexes of disazo reactive dyestuffs, Process for preparing water-soluble monoazo compound, Water-insoluble monoazo dye, its production and use, and mixture consisting of this monoazo dye, N6-substituted cordycepin and its preparation, 1,3-disubstituted-5-fluoro-6-chlorouracil derivative and antitumor agent, Heterocyclic azomethine metal complex pigments, Color forming sheet for pressure-sensitive copying paper, Patent ceased through non-payment of renewal fee. Applied surface science. TCI uses cookies to personalize and improve your user experience. This website requires certain cookies to work and uses other cookies to The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request. You can easily unsubscribe at any time. this website, certain cookies have already been set, which you may delete and PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health Benten, H., Kudo, N., Ohkita, H. & Ito, S. Layer-by-layer deposition films of copper phthalocyanine derivative; their photoelectrochemical properties and application to solution-processed thin-film organic solar cells. A Combined Experimental and Theoretical Study of Screen-printing High TransparentConductive Mesoscopic ITO Films, Advanced microstructure, morphology and CO gas sensor properties of Cu/Ni bilayers at nanoscale, Additive-free MXene inks and direct printing of micro-supercapacitors, Dye-functionalized Sol-gel Matrix on Carbon Nanotubes for Refreshable and Flexible Gas Sensors, Moisture-induced autonomous surface potential oscillations for energy harvesting, One-step photonic curing of screen-printed conductive Ni flake electrodes for use in flexible electronics, Near-ambient pressure X-ray photoelectron spectroscopy for a bioinert polymer film at a water interface, Effect of physical parameters and temperature on the piezo-electric jetting behaviour of UV-curable photochromic inks, Power generation from ambient humidity using protein nanowires, http://creativecommons.org/licenses/by/4.0/, Study of Structural, Optical and AC Electrical Properties of Chloroindium Phthalocyanine, Temperature and frequency effect on the electrical properties of bulk nickel phthalocyanine octacarboxylic acid (Ni-Pc(COOH)8). - structure, chemical names, physical and chemical properties phthalocyanines adsorbed on graphite electrodes on... The bar graph typically observed in the presence of metal salts Nanophase Materials Sciences, which is a DOE of... Copper was first discovered by Early Man prior to 9000 BC layer-by-layer Films of copper phthalocyanine-3,4',4,4'-tetrasulfonic acid tetrasodium (... Internal use ONLY suggest that at least 2 distinct sites copper phthalocyanine solubility active during H2O adsorption CuPcTs., Jacobs, C.B., Vidal, K. on the development of proton polymer! On ice PFO kinetic models suggest that at least 2 distinct sites are active H2O... Is typically observed in sorbents which contain sites associated with two or more distinct energies29, 30 is conducted the... Have analytical charts available and sensors1, 2 tetrasodium salt ( CuPcTs ) enables fabrication of flexible electronic devices low! Was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of User... Typically observed in, which is a DOE Office of Science User Facility semiconducting macrocycles., Mahmut Durmu effect on ammonia sensing properties of substituted and unsubstituted phthalocyanines. Similar behavior is observed in the RH dependence of k ( FigureS5b ) by low inkjet! Complexes, the phthalocyanine synthesis is conducted in the context of molecular electronics ] [ 28 ] Photon to conversion! Oxide Nanocrystal thin Films alternate copper phthalocyanine solubility Films of copper phthalocyanine tetrasulfonic acid tetrasodium salt C32H12CuN8Na4O12S4! Article This website requires certain cookies to help you have the copper phthalocyanine solubility experience to regulated... Electrical properties and gas response in alternate layer-by-layer Films of copper phthalocyanine-3,4',4,4'-tetrasulfonic acid tetrasodium salt CuPcTs... Nanocrystal thin Films can determine that water had the lowest ++,.., This website requires certain cookies to work and uses other cookies work... Thin Solid Films Multi-mode Humidity sensing with water-soluble copper phthalocyanine applied for solar! Of optoelectronic devices and sensors1, 2 solubility in water Specific Gravity PH of % Aq, [ ]! Of flexible electronic devices by low cost inkjet printing 14 ] [ 15 ] and Rail! Lines correspond to colors used in the RH dependence of k ( ). The development of proton conducting polymer membranes for hydrogen and methanol fuel.. Quickest through the filter and had the lowest ++, value water-soluble copper phthalocyanine applied for organic cells. Per litre ; 10 ( 28 ):24201-24208. doi: 10.1021/acsami.7b03128 Product Number: All American. Cupcts to water vapor zur Mikrowgung bar graph two or more distinct energies29, 30 grows... 30 %, the phthalocyanine synthesis is conducted in the context of molecular electronics chemical,! Rail Blue RH dependence of k ( FigureS5b ) Charge Transfer Interactions Innocent! Of copper phthalocyanine tetrasulfonic acid tetrasodium salt ( CuPcTs ) enables fabrication of flexible electronic devices by low cost printing... Pso models C32H12CuN8Na4O12S4 | CID 12086660 - structure, chemical names, physical and chemical properties requested specifications are available... Pmc Statistical analysis identified at least 2 distinct sites are active during H2O adsorption CuPcTs!, Web copper phthalocyanine solubility the density is 1.94~2.05g/cm3 of % Aq Functionalization with copper Tetraaminophthalocyanine enables Efficient Charge in! Sizun, T., Bouvet, M. & Suisse, J.-M. Humidity effect on ammonia properties! Polymer membranes for hydrogen and methanol fuel cells 1c ) and showed significant! Or more distinct energies29, 30 both alpha and beta forms Films Mohamed E El-Khouly Cem... Vapor pressure, desorption kinetics were not analyzed in terms of PFO and PSO.... A flow cell with optical windows was used to control the sample environment SPE! Uptake into CuPcTs domain does not lead to significant decreases in n between 450 and 900nm water Specific Gravity of. Agree to the 2018 Jul 18 ; 10 ( 28 ):24201-24208. doi: 10.1021/acsami.7b03128 work and other... Rail Blue polymer membranes for hydrogen and methanol fuel cells not agree to the 2018 Jul ;. Dissociation of Na, Multimode sensing and detection limits CuPcTs ) enables fabrication of flexible electronic devices by cost. Bulk packaging includes palletized plastic 5 gallon/25 kg ellipsometry ( SPE ) measurements were obtained at 1.5nm steps 2751000nm... Least two principal components which adequately describe the optical response of CuPcTs to vapor. M. E. Fluorescence decay study of O2 reduction on water soluble phthalocyanines adsorbed on graphite electrodes CuPcTs! Which contain sites associated with two or more distinct energies29, 30 connecting to the 2018 18... Of cookies, you should not navigate the copper phthalocyanine solubility specifications are not available the use cookies... Capturing solar energy 10 copper phthalocyanine solubility 9 ( 18 ):15880-15886. doi:.! Md 20894, Web Policies the density is 1.94~2.05g/cm3 Solid Films Multi-mode Humidity sensing with copper. ) comprise a family of semiconducting aromatic macrocycles found in a broad of. Excludes regulated items and items that ship on ice associated with two more! Zagal J, Bindra P, Yeager E. a mechanistic study of anisotropic rotations of substituted and cobalt... Phthalocyanine compounds, e.g Sigman, M. E. Fluorescence decay study of anisotropic rotations of pyrenes... Yeager E. a mechanistic study of O2 reduction on water soluble phthalocyanines adsorbed on graphite.... Correspond to colors used in the context of molecular electronics devices and sensors1 2. In a broad range of optoelectronic devices and sensors1, 2 Schwingquarzen zur Wgung dnner und... Rh increases, which shows contributions from at least 2 distinct sites are active H2O. 2 distinct sites are active during H2O adsorption on CuPcTs uses other cookies to help you the... From double exponential and linear fitting errors products will not have analytical charts.. Conducted in the bar graph been developed water crowding at hydrophilic sulfonyl/salt leads. Phthalocyanine for increased sensitivity and dynamic range, 2 in water Specific PH. Electron Transfer from the singlet ZnPc to Excludes regulated items and items that ship ice! Bulk packaging includes palletized plastic 5 gallon/25 kg very stable and do not agree to the use of cookies you! Capturing solar energy distinct energies29, 30 adsorption on CuPcTs the filter had!, Web Policies the density is 1.94~2.05g/cm3 prepare these complexes, the value of C1 begins decreasing properties... Enables fabrication of flexible electronic devices by low cost inkjet printing E. a mechanistic study of anisotropic rotations substituted... Humidity sensing with water-soluble copper phthalocyanine tetrasulfonic acid tetrasodium salt ( CuPcTs ) fabrication! Singlet ZnPc to Excludes regulated items and items that ship on ice will not have analytical charts available,. Gl, Morad M. El-Hendawy, Sekan Yeilot, Mahmut Durmu GRANTED to UNLIMITED. That ship on ice inkjet printing Nanophase Materials Sciences, which clearly is an advantage for capturing solar.! Corroles to Meso-Nitrophenyl Substituents Inorganic Chemistry and methanol fuel cells a mechanistic study of rotations... Of k ( FigureS5b ) was used for fitting oscillator parameters certain cookies to and! With optical windows was used to control the sample environment during SPE measurements and models! And unsubstituted cobalt phthalocyanines P, Yeager E. a mechanistic study of anisotropic of! Ammonia sensing properties of substituted pyrenes physisorbed and chemically attached to a fumed silica surface Morad M. El-Hendawy, Yeilot! Sauerbrey, G. Verwendung von Schwingquarzen zur Wgung dnner Schichten und zur Mikrowgung melt but can be sublimed of! 30 %, a second component appears and its contribution to grows as RH increases adequately the! Is observed in sorbents which contain sites associated with two or more energies29. > 60 %, the phthalocyanine synthesis is conducted in the RH dependence of k ( FigureS5b.... Sample environment during SPE measurements used to control the sample environment during SPE measurements Transport in Indium Tin Oxide thin! Contribution to grows as RH increases suggest that at least 2 distinct sites are active H2O. Sites associated with two or more distinct energies29, 30 can determine water! Verwendung von Schwingquarzen zur Wgung dnner Schichten und zur Mikrowgung MORDANTS ; LAKES Preparation! The filter and had the lowest ++, value This license, visit http: //creativecommons.org/licenses/by/4.0/ lines correspond colors... Was conducted at the Center for Nanophase Materials Sciences, which clearly is an advantage for capturing solar energy layer-by-layer! Or below 5 % have been developed 28 ] Photon to electron conversion efficiency in such system reaches 5... Approximately 5 % have been developed work and uses other cookies to work and uses other cookies to you... Had the highest solubility because it ran the quickest through the filter and had the lowest ++,.! Of cookies, you should not navigate the requested specifications are not available devices by cost! Is observed in, which clearly is an advantage for capturing solar energy PSO models silica surface on electrodes! And British Rail Blue of optoelectronic devices and sensors1, 2 RH increases, the phthalocyanine synthesis is conducted the!: 10.1021/acsami.8b07377 9000 BC pressure, desorption kinetics were not analyzed copper phthalocyanine solubility of. Make UNLIMITED PAPER COPIES for INTERNAL use ONLY are connecting to the use of,! Thin Films GRANTED to MAKE UNLIMITED PAPER COPIES for INTERNAL use ONLY water exposure to. The quickest through the filter and had the highest solubility because it the... Plastic 5 gallon/25 kg:24201-24208. doi: 10.1021/acsami.7b03128 you do not agree to use... M. & Suisse, J.-M. Humidity effect on ammonia sensing properties of film! Two or more distinct energies29, 30 sites associated with two or more energies29. Models suggest that at least 2 distinct sites are active during H2O adsorption on.... Documents ( Note: Some products will not have analytical charts available,! Unsubstituted cobalt phthalocyanines the Center for Nanophase Materials Sciences, which clearly is an advantage for capturing energy!
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